专利名称 | 変性ZSM?5分子篩触媒によるメタノ ルカップリングのナフサ接触分解反応の触媒法 | 申请号 | JP20130546565 | 专利类型 | JP | 公开(公告)号 | JP5756867(B2) | 公开(授权)日 | 2015.07.29 | 申请(专利权)人 | 中国科学院大连化学物理研究所 | 发明(设计)人 | ▲劉 中民;魏迎旭;▲斉 越;叶茂;李▲銘 芝;李冰;王▲賢 高;何▲長 青;▲孫 新▲徳 | 主分类号 | C07C4/06 | IPC主分类号 | C07C4/06;B01J29/40;C07C11/04;C07C11/06;C07C11/08 | 专利有效期 | 変性ZSM?5分子篩触媒によるメタノ ルカップリングのナフサ接触分解反応の触媒法 至変性ZSM?5分子篩触媒によるメタノ ルカップリングのナフサ接触分解反応の触媒法 | 法律状态 | 说明书摘要 | The present invention provides a process for methanol coupled catalytic cracking reaction of naphtha using a modified ZSM-5 molecular sieve catalyst, comprising performing a co-feeding reaction of methanol and naphtha on the modified ZSM-5 molecular sieve catalyst to produce low carbon olefins and/or aromatic hydrocarbons. In the process, the modified ZSM-5 molecular sieve catalyst comprises, in term of weight percent, 25-80wt% of a ZSM-5 molecular sieve, 15-70wt% of a binder, and 2.2-6.0wt% of lanthanum and 1.0-2.8wt% of phosphorus loaded on the ZSM-5 molecular sieve. The naphtha comprises 63.8-89.5 wt% of saturated chain alkanes and 5.6-29.8wt% of cyclic alkanes. The naphtha and methanol concurrently pass through the catalyst bed, which are reacted during contacting with the catalyst under a reaction condition of a reaction temperature of 550-670°C, a mass ratio of methanol to naphtha of 0.05-0.8, and a total mass space velocity of naphtha and methanol of 1.0-5 h -1 . |
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