合成ガス転化用リン化物触媒、その製造方法及び応用

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专利名称 合成ガス転化用リン化物触媒、その製造方法及び応用 申请号 JP20140523180 专利类型 JP 公开(公告)号 JP5788598(B2) 公开(授权)日 2015.10.07 申请(专利权)人 中国科学院大连化学物理研究所 发明(设计)人 丁雲傑;宋憲根;陳維苗;厳麗;呂元 主分类号 B01J27/185 IPC主分类号 B01J27/185;B01J32/00;B01J37/08;B01J37/18;C10G2/00 专利有效期 合成ガス転化用リン化物触媒、その製造方法及び応用 至合成ガス転化用リン化物触媒、その製造方法及び応用 法律状态 说明书摘要 This invention provides a phosphide catalyst for syngas conversion and the production method and use thereof, more specifically, to a catalyst for converting a syngas raw material into oxygenates, comprising one or more metallic Fe, Co, Ni and their phosphides, the production method of the catalyst and its use in the reaction of converting a syngas raw material into hydrocarbons and oxygenates. According to the invention, a catalyst for converting H 2 /CO into hydrocarbons and oxygenates, supported by SiO 2 or Al 2 O 3 and comprising one or more metallic Fe, Co, Ni and their phosphides under certain reaction temperatures and pressures is provided. The catalysts are consisted of two parts of an active component and a support. The active component is a mixture consisted of one or more of metallic Fe, Co, Ni and their phosphides. The support is selected from SiO 2 or Al 2 O 3 . In a fix-bed or slurry bed reactor, H 2 /CO can be converted into oxygenates having two carbons or more and hydrocarbons with high activity and high selectivity, under certain reaction temperatures and pressures and the action of the catalyst in the invention.

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