| 专利名称 | Multi-metallic bulk catalyst with layered structure and method for the preparation and use thereof | 申请号 | US201013202517 | 专利类型 | US | 公开（公告）号 | US9457342(B2) | 公开（授权）日 | 2016.10.04 | 申请（专利权）人 | 中国科学院大连化学物理研究所 | 发明（设计）人 | Li Can;Jiang Zongxuan;Wang Lu;Zhang Yongna;Zhang Yuliang | 主分类号 | C01G29/00 | IPC主分类号 | C01G29/00;B01J21/02;B01J23/888;B01J35/02;B01J37/08;B01J23/755;B01J23/00;B01J37/02;B01J37/04;B01J37/20;C10G45/04 | 专利有效期 | Multi-metallic bulk catalyst with layered structure and method for the preparation and use thereof 至Multi-metallic bulk catalyst with layered structure and method for the preparation and use thereof | 法律状态 | 说明书摘要 | The invention discloses a multi-metallic bulk catalyst with layered structure, wherein the metals in the multi-metallic bulk catalyst is consisted of a Group VIII metal MI, at least one metal MII with the valence of +3 and at least two Group VIB metals MIII+MIV, wherein (the mole number of MI+the mole number of MII):(the mole number of MIII+the mole number of MIV) is from 1:9 to 9:1; the mole number of MI:the mole number of MII is from 1:5 to 5:1; and the mole number of MIII:the mole number of MIV is from 1:5 to 5:1. The invention also discloses the preparation method and use of the above catalyst. The invention is use for the hydrodesulfurization of diesel distillate including 4,6-dimethyldibenzothiophene, wherein the catalyst exhibits a extreme high hydrodesulfurization activity. Thus, the ultra-deep hydrodesulfurization is achieved and the cost of the bulk catalyst is reduced. |
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