Process for preparing a terpolymer of tetrafluoroethylene, ethylene and a third monomer

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专利名称 Process for preparing a terpolymer of tetrafluoroethylene, ethylene and a third monomer 申请号 US84679586A 专利类型 US 公开(公告)号 US4678847A 公开(授权)日 1987.07.07 申请(专利权)人 中国科学院上海有机化学研究所 发明(设计)人 ZHANG YUN-XIANG ; DAI XING-YI ; LU ZHI-KANG ; ZENG SEN 主分类号 C08F210/02 IPC主分类号 C08F210/02 专利有效期 Process for preparing a terpolymer of tetrafluoroethylene, ethylene and a third monomer 至Process for preparing a terpolymer of tetrafluoroethylene, ethylene and a third monomer 法律状态 说明书摘要 The present invention relates to the process for preparing terpolymer of tetrafluoroethylene (TFE), ethylene (E), and a third monomer. According to the present invention, dicarbonate peroxide is used as initiator, 1,1,2-trichloro-1,2,2-trifluoro-ethane as the reaction medium and compounds of molecular formula CnR2n+2, wherein, n=0,1, or 2;R=H, Cl or F, are gaseous chain telomeric agents to control the average molecular weight of copolymers, the formula of third monomer is CF2XCOCF2 X' or wherein X=X'=Cl or F, R1=CF3 or CH3,R2=CF3, CH3 or H, and R3=H or F, usually the molar ratio of TFE to E is from 60:40 to 40:60 with the content of the third monomer being from 0.1% to 10%, based on the total molar amount of TFE and E.

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