| 专利名称 | Catalyst combination and process for the low-temperature co-production of methanol and methyl formate in liquid phase | 申请号 | US19980145735 | 专利类型 | US | 公开（公告）号 | US6090741 | 公开（授权）日 | 2000.07.18 | 申请（专利权）人 | 中国科学院成都有机化学有限公司 | 发明（设计）人 | WU YUTANG (CN); LUO SHIZHONG (CN); LIU XINGQUAN (CN); CHEN WENKAI (CN); JIA CHAOXIA (CN); LI SHUNFEN (CN); YU ZUOLONG (CN) | 主分类号 | B01J31/00 | IPC主分类号 | B01J31/00 | 专利有效期 | Catalyst combination and process for the low-temperature co-production of methanol and methyl formate in liquid phase 至Catalyst combination and process for the low-temperature co-production of methanol and methyl formate in liquid phase | 法律状态 | 说明书摘要 | The present invention relates to a novel catalyst combination and a novel process for the synthesis of methanol and methyl formate (MF), and more specifically to the production of methanol and MF by contacting syngas under relatively mild conditions in a slurry phase with the novel catalyst combination comprising unreduced copper chromite prepared using specifical method, alkali alcoholates, a nonionics and a non-polar solvent. The nonionics, for example, C8H17-(C6H4)-O-(C2H4O)nH (where n is between 4 and 60) is used in the amount that is at least 5 vol. % of the slurry (liquid reaction medium). And the non-polar solvent having a dielectricity constant between 2 and 3 at 20 DEG C. is used in the amount that is at least 50 vol. % of the slurry. The present invention allows the synthesis of methanol and MF to occur in the temperature range of approximately 100-150 DEG C., and the pressure range of 3-8 MPa. The process produces methanol and MF with up to 95% syngas conversion per pass and up to 99% selectivity to methanol and MF. Very small amount of water, carbon dioxide and dimethyl ether is also produced. A space-time-yield of 88.3 gms./L/h is achieved when using a continuous stirring tank reactor(CSTR). A tubular slurry reactor of 10 liter volume without any mechanical agitator has been successfully used. The present catalyst combination also is capable of tolerating fluctuations in the H2/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation. |
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