专利名称 | Catalyst for ultra-deep desulfurization of diesel via oxidative distillation, its preparation and desulfurization method | 申请号 | US20080665905 | 专利类型 | US | 公开(公告)号 | US8394735(B2) | 公开(授权)日 | 2013.03.12 | 申请(专利权)人 | 中国科学院大连化学物理研究所 | 发明(设计)人 | JIANG ZONGXUANLI CANZHANG YONGNALV HONGYIN | 主分类号 | C10G57/00 | IPC主分类号 | C10G57/00 | 专利有效期 | Catalyst for ultra-deep desulfurization of diesel via oxidative distillation, its preparation and desulfurization method 至Catalyst for ultra-deep desulfurization of diesel via oxidative distillation, its preparation and desulfurization method | 法律状态 | 说明书摘要 | A catalyst for ultra-deep desulfurization of diesel via oxidative distillation is an amphiphilic oxidative catalyst, which is expressed as Qm[XMnOq], wherein 1?m?12; 9?n?18; 34?q?62; Q is a quaternary ammonium cation; X is P, Si, As or B; and M is Mo) or W. A desulfurization method comprises a) mixing well a diesel, the amphiphilic catalyst, and hydrogen peroxide, reacting for 10-300 minutes at ambient temperature and normal pressure, transforming the sulfur-containing compounds in the diesel into sulfone to obtain an oxidized diesel; b) distilling the oxidized diesel obtained in step a) under reduced pressure to obtain the ultra-low sulfur diesel having a sulfur content of less than 10 ppm; and c) separating and recovering the catalyst and sulfone. |
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