Catalyst for ultra-deep desulfurization of diesel via oxidative distillation, its preparation and desulfurization method

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专利名称 Catalyst for ultra-deep desulfurization of diesel via oxidative distillation, its preparation and desulfurization method 申请号 US20080665905 专利类型 US 公开(公告)号 US8394735(B2) 公开(授权)日 2013.03.12 申请(专利权)人 中国科学院大连化学物理研究所 发明(设计)人 JIANG ZONGXUANLI CANZHANG YONGNALV HONGYIN 主分类号 C10G57/00 IPC主分类号 C10G57/00 专利有效期 Catalyst for ultra-deep desulfurization of diesel via oxidative distillation, its preparation and desulfurization method 至Catalyst for ultra-deep desulfurization of diesel via oxidative distillation, its preparation and desulfurization method 法律状态 说明书摘要 A catalyst for ultra-deep desulfurization of diesel via oxidative distillation is an amphiphilic oxidative catalyst, which is expressed as Qm[XMnOq], wherein 1?m?12; 9?n?18; 34?q?62; Q is a quaternary ammonium cation; X is P, Si, As or B; and M is Mo) or W. A desulfurization method comprises a) mixing well a diesel, the amphiphilic catalyst, and hydrogen peroxide, reacting for 10-300 minutes at ambient temperature and normal pressure, transforming the sulfur-containing compounds in the diesel into sulfone to obtain an oxidized diesel; b) distilling the oxidized diesel obtained in step a) under reduced pressure to obtain the ultra-low sulfur diesel having a sulfur content of less than 10 ppm; and c) separating and recovering the catalyst and sulfone.

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